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Yan Zhang, Jian Xiao, Qiying Lv, Shuai Wang
《化学科学与工程前沿(英文)》 2018年 第12卷 第3期 页码 494-508 doi: 10.1007/s11705-018-1732-9
Electrolytic water splitting has been considered as a promising technology to produce highly pure H2 by using electrical power produced from wind, solar energy or other fitful renewable energy resources. Combining novel self-supporting structure and high-performance transition metal phosphides (TMP) shows substantial promise for practical application in water splitting. In this review, we try to provide a comprehensive analysis of the design and fabrication of various self-supported TMP electrodes for hydrogen evolution reaction, which are divided into three categories: catalysts growing on carbon-based substrates, catalysts growing on metal-based substrates and freestanding catalyst films. The material structures together with catalytic performances of self-supported electrodes are presented and discussed. We also show the specific strategies to further improve the catalytic performance by elemental doping or incorporation of nanocarbons. The simple and one-step methods to fabricate self-supported TMP electrodes are also highlighted. Finally, the challenges and perspectives for self-supported TMP electrodes in water splitting application are briefly discussed.
关键词: transition metal phosphide self-supported electrode electrocatalysis hydrogen evolution reaction
《化学科学与工程前沿(英文)》 2023年 第17卷 第4期 页码 437-448 doi: 10.1007/s11705-022-2228-1
关键词: molybdenum oxides oxygen vacancies heterostructure electrocatalysts hydrogen evolution reaction
Application of electrode materials and catalysts in electrocatalytic treatment of dye wastewater
《化学科学与工程前沿(英文)》 2021年 第15卷 第6期 页码 1427-1443 doi: 10.1007/s11705-021-2108-0
关键词: electrocatalytic oxidation electrode electrocatalysis dye wastewater
Quality control based on electrode displacement and force in resistance spot welding
Chuntao JI, Lipeng DENG
《机械工程前沿(英文)》 2010年 第5卷 第4期 页码 412-417 doi: 10.1007/s11465-010-0114-x
关键词: aluminum electrode displacement electrode force nugget size data acquisition
A novel flow electrode capacitive deionization device with spindle-shaped desalting chamber
《环境科学与工程前沿(英文)》 2023年 第18卷 第4期 doi: 10.1007/s11783-024-1800-y
● A spindle-shaped influent chamber was designed and equipped in FCDI system.
关键词: Spindle-shaped chamber Desalination performance Flow electrode capacitive deionization
Arunkumar JAYAKUMAR
《能源前沿(英文)》 2019年 第13卷 第2期 页码 325-338 doi: 10.1007/s11708-019-0618-y
关键词: PEM fuel cell gas diffusion electrode(GDE) gas diffusion layer(GDL) membrane electrode assembly durability fuel cell catalyst
《化学科学与工程前沿(英文)》 2023年 第17卷 第8期 页码 1065-1074 doi: 10.1007/s11705-023-2313-0
Characterization of electrode fouling during electrochemical oxidation of phenolic pollutant
Xuefeng Liu, Shijie You, Fang Ma, Hao Zhou
《环境科学与工程前沿(英文)》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1345-7
关键词: Electro-oxidation Electrode fouling Polymeric film Chloride ions
Miaomiao Tong, Lei Wang, Peng Yu, Xu Liu, Honggang Fu
《化学科学与工程前沿(英文)》 2018年 第12卷 第3期 页码 417-424 doi: 10.1007/s11705-018-1711-1
A highly active bi-functional electrocatalyst towards both hydrogen and oxygen evolution reactions is critical for the water splitting. Herein, a self-supported electrode composed of 3D network nanostructured NiCoP nanosheets grown on N-doped carbon coated Ni foam (NiCoP/NF@NC) has been synthesized by a hydrothermal route and a subsequent phosphorization process. As a bifunctional electrocatalyst, the NiCoP/NF@NC electrode needs overpotentials of 31.8 mV for hydrogen evolution reaction and 308.2 mV for oxygen evolution reaction to achieve the current density of 10 mA·cm−2 in 1 mol·L−1 KOH electrolyte. This is much better than the corresponding monometal catalysts of CoP/NF@NC and NiP/NF@NC owing to the synergistic effect. NiCoP/NF@NC also exhibits low Tafel slope, and excellent long-term stability, which are comparable to the commercial noble catalysts of Pt/C and RuO2.
关键词: bimetallic phosphides N-doped carbon self-support hydrogen evolution oxygen evolution
《环境科学与工程前沿(英文)》 2023年 第17卷 第8期 doi: 10.1007/s11783-023-1697-x
● Titanium-based flow-through electrode achieved high Cr(VI) reduction efficiency.
关键词: Flow-through electrode Hexavalent chromium Heavy metals Neural network Artificial intelligence
Latest development of double perovskite electrode materials for solid oxide fuel cells: a review
Shammya AFROZE, AfizulHakem KARIM, Quentin CHEOK, Sten ERIKSSON, Abul K. AZAD
《能源前沿(英文)》 2019年 第13卷 第4期 页码 770-797 doi: 10.1007/s11708-019-0651-x
关键词: double perovskites electrode materials hydrocarbon fuel solid oxide fuel cells
《环境科学与工程前沿(英文)》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1518-7
• Antibiotic azithromycin employed in graphite electrode for EAB biosensor.
关键词: AZM@GP composite electrode EAB-biosensor Water quality early-warning
《化学科学与工程前沿(英文)》 2023年 第17卷 第10期 页码 1440-1449 doi: 10.1007/s11705-023-2333-9
关键词: MXene supercapacitor cobalt doping structure characterization electrochemical performance
ZHANG Pengxian, ZHANG Hongjie, CHEN Jianhong, MA Yuezhou
《机械工程前沿(英文)》 2007年 第2卷 第3期 页码 330-335 doi: 10.1007/s11465-007-0058-y
Preparation of a Pb loaded gas diffusion electrode and its application to CO
Ang LI, Hua WANG, Jinyu HAN, Li LIU
《化学科学与工程前沿(英文)》 2012年 第6卷 第4期 页码 381-388 doi: 10.1007/s11705-012-1216-2
关键词: electroreduction carbon dioxide lead catalyst gas diffusion electrode formic acid
标题 作者 时间 类型 操作
Self-supported transition metal phosphide based electrodes as high-efficient water splitting cathodes
Yan Zhang, Jian Xiao, Qiying Lv, Shuai Wang
期刊论文
Oxygen-deficient MoO/NiS heterostructure grown on nickel foam as efficient and durable self-supported
期刊论文
Application of electrode materials and catalysts in electrocatalytic treatment of dye wastewater
期刊论文
Quality control based on electrode displacement and force in resistance spot welding
Chuntao JI, Lipeng DENG
期刊论文
A comprehensive assessment on the durability of gas diffusion electrode materials in PEM fuel cell stack
Arunkumar JAYAKUMAR
期刊论文
Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors
期刊论文
Characterization of electrode fouling during electrochemical oxidation of phenolic pollutant
Xuefeng Liu, Shijie You, Fang Ma, Hao Zhou
期刊论文
3D Network nanostructured NiCoP nanosheets supported on N-doped carbon coated Ni foam as a highly active
Miaomiao Tong, Lei Wang, Peng Yu, Xu Liu, Honggang Fu
期刊论文
Electroreduction of hexavalent chromium using a porous titanium flow-through electrode and intelligent
期刊论文
Latest development of double perovskite electrode materials for solid oxide fuel cells: a review
Shammya AFROZE, AfizulHakem KARIM, Quentin CHEOK, Sten ERIKSSON, Abul K. AZAD
期刊论文
An antibiotic composite electrode for improving the sensitivity of electrochemically active biofilm biosensor
期刊论文
Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element
期刊论文
Quality monitoring of resistance spot welding based on electrode displacement characteristics analysis
ZHANG Pengxian, ZHANG Hongjie, CHEN Jianhong, MA Yuezhou
期刊论文